The Old Hume Highway by The Roads & Maritime Services NSW
The 
of NSW has a guide on the "The Old Hume Highway, History begins with a road"
This guide covers some of the history of the old highway and the towns it went though in NSW, from Ashfield (In Sydney) to Albury (NSW/VIC Border), It is also a self-guided tour guide.
This guide is available for download by clicking the image below.
Or visiting R&M Site
(PDF, 10.5 MB)